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Crystal structure of 2-{[(naphthalen-1-yl)oxy]meth-yl}-5-(2,4,5-tri-fluoro-phen-yl)-1,3,4-oxa-diazole.

ABSTRACT: In the title compound C19H11F3N2O2, the oxa-diazole ring and the naphthalene ring system are approximately planar (r.m.s. deviations of 0.001 and 0.020?Å, respectively) and the oxa-diazole ring makes dihedral angles of 13.11?(1) and 7.59?(1)° with the naphthalene ring system and the tri-fluoro-phenyl ring, respectively. In the crystal, C-H?N hydrogen bonds link mol-ecules into chains along the a-axis direction, while C-H?F contacts form additional chains along the ac diagonal. These contacts generate sheets of mol-ecules approximately parallel to the (011) plane.

SUBMITTER: Govindhan M

PROVIDER: S-EPMC4350736 | biostudies-literature | 2015 Mar

REPOSITORIES: biostudies-literature

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Crystal structure of 2-{[(naphthalen-1-yl)oxy]meth-yl}-5-(2,4,5-tri-fluoro-phen-yl)-1,3,4-oxa-diazole.

Govindhan Muniyappan M Subramanian Kathavarayan K Viswanathan Vijayan V Velmurugan Devadasan D

Acta crystallographica. Section E, Crystallographic communications 20150221 Pt 3

In the title compound C19H11F3N2O2, the oxa-diazole ring and the naphthalene ring system are approximately planar (r.m.s. deviations of 0.001 and 0.020 Å, respectively) and the oxa-diazole ring makes dihedral angles of 13.11 (1) and 7.59 (1)° with the naphthalene ring system and the tri-fluoro-phenyl ring, respectively. In the crystal, C-H⋯N hydrogen bonds link mol-ecules into chains along the a-axis direction, while C-H⋯F contacts form additional chains along the ac diagonal. These contacts gen ...[more]

PMID: 25844242

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