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Crystal structure of methyl N-ferro-cenyl-carbamate.

ABSTRACT: The asymmetric unit of the title compound, [Fe(C5H5)(C7H8NO2)], contains two independent mol-ecules consisting of a ferrocenyl moiety and a nitro-gen-bound methyl carbamate. These units are almost perpendicular to each other, making dihedral angles of 87.74?(9) and 87.32?(8)°. In each independent mol-ecule, the cyclo-penta-dienyl rings deviate slightly from an eclipsed conformation and lie virtually parallel [dihedral angles = 1.42?(15) and 0.49?(13)°]. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds into chains along the a-axis direction.

SUBMITTER: Rodriguez AJ

PROVIDER: S-EPMC4384608 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of methyl N-ferro-cenyl-carbamate.

Rodríguez Alan J AJ Quirke J Martin E JM Diouf Aida O AO

Acta crystallographica. Section E, Crystallographic communications 20150117 Pt 2

The asymmetric unit of the title compound, [Fe(C5H5)(C7H8NO2)], contains two independent mol-ecules consisting of a ferrocenyl moiety and a nitro-gen-bound methyl carbamate. These units are almost perpendicular to each other, making dihedral angles of 87.74 (9) and 87.32 (8)°. In each independent mol-ecule, the cyclo-penta-dienyl rings deviate slightly from an eclipsed conformation and lie virtually parallel [dihedral angles = 1.42 (15) and 0.49 (13)°]. In the crystal, mol-ecules are linked by N ...[more]

PMID: 25878840

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