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Crystal structure of (E)-3-{[2-(2,4-di-chloro-benzyl-idene)hydrazin-1-yl]carbon-yl}pyridinium chloride trihydrate.

ABSTRACT: In the title hydrated salt, C13H10Cl2N3O(+)·Cl(-)·3H2O, the organic cation exhibits a dihedral angle of 8.26?(14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70?(15) and 15.93?(5)° between the mean planes of the hydrazide group and the benzene and pyridinium rings, respectively. In the crystal, N-H?O, N-H?Cl, C-H?O, C-H?Cl, O-H?O, O-H?N and O-H?Cl hydrogen bonds link the complex cations, chloride anions and solvent water mol-ecules into a three-dimensional network.

SUBMITTER: Novina JJ

PROVIDER: S-EPMC4384619 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of (E)-3-{[2-(2,4-di-chloro-benzyl-idene)hydrazin-1-yl]carbon-yl}pyridinium chloride trihydrate.

Novina J Josephine JJ Vasuki G G Suresh M M Padusha M Syed Ali MS

Acta crystallographica. Section E, Crystallographic communications 20150110 Pt 2

In the title hydrated salt, C13H10Cl2N3O(+)·Cl(-)·3H2O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and pyridinium rings, respectively. In the crystal, N-H⋯O, N-H⋯Cl, C-H⋯O, C-H⋯Cl, O-H⋯O, O-H⋯N and O-H⋯Cl hydrogen bonds link the complex cations, chloride anions and solvent water mol-ecules into a three-dimensio ...[more]

PMID: 25878853

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