Ontology highlight
ABSTRACT:
SUBMITTER: Vollmer MV
PROVIDER: S-EPMC4399245 | biostudies-literature | 2014 Sep
REPOSITORIES: biostudies-literature
Vollmer Matthew V MV Machan Charles W CW Clark Melissa L ML Antholine William E WE Agarwal Jay J Schaefer Henry F HF Kubiak Clifford P CP Walensky Justin R JR
Organometallics 20140901 1
The synthesis and characterization of new Mn(I)- and Re(I)-centered organometallic complexes fashioned with 1,4-diazabutadiene (DAB) ligands is reported. Ten compounds of the type <i>fac</i>-(α-diimine)M(CO)<sub>3</sub>Br (M = Mn, Re) were obtained in moderate to excellent yield (35-80%) and high purity from the coordination of the five ligands with M(CO)<sub>5</sub>Br in refluxing ethanol. Despite the electronic similarity of DAB to 2,2'-bipyridyl, the complexes described herein were poor media ...[more]