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Accessing near-infrared-absorbing BF2-azadipyrromethenes via a push-pull effect.


ABSTRACT: Novel aza-BODIPYs with significant bathochromic shifts were designed and synthesized by installation of strong electron-withdrawing groups on the para-positions of 1,7-phenyls and electron-donating groups on the para-positions of 3,4-phenyls. These dyes show strong NIR fluorescence emissions up to 756 nm, and absorptions up to 720 nm.

SUBMITTER: Jiao L 

PROVIDER: S-EPMC4415601 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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Accessing near-infrared-absorbing BF2-azadipyrromethenes via a push-pull effect.

Jiao Lijuan L   Wu Yayang Y   Wang Sufan S   Hu Xiaoke X   Zhang Ping P   Yu Changjiang C   Cong Kebing K   Meng Qianli Q   Hao Erhong E   Vicente M Graça H MG  

The Journal of organic chemistry 20140206 4


Novel aza-BODIPYs with significant bathochromic shifts were designed and synthesized by installation of strong electron-withdrawing groups on the para-positions of 1,7-phenyls and electron-donating groups on the para-positions of 3,4-phenyls. These dyes show strong NIR fluorescence emissions up to 756 nm, and absorptions up to 720 nm. ...[more]

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