Dataset Information
Eosin Y-catalyzed visible-light-mediated aerobic oxidative cyclization of N,N-dimethylanilines with maleimides.
Ontology highlight
ABSTRACT:
SUBMITTER: Liang Z
PROVIDER: S-EPMC4419562 | biostudies-literature | 2015
REPOSITORIES: biostudies-literature
Publications
Eosin Y-catalyzed visible-light-mediated aerobic oxidative cyclization of N,N-dimethylanilines with maleimides.
Beilstein journal of organic chemistry 20150401
A novel and simple strategy for the efficient synthesis of the corresponding tetrahydroquinolines from N,N-dimethylanilines and maleimides using visible light in an air atmosphere in the presence of Eosin Y as a photocatalyst has been developed. The metal-free protocol involves aerobic oxidative cyclization via sp(3) C-H bond functionalization process to afford good yields in a one-pot procedure under mild conditions. ...[more]