Unknown

Dataset Information

0

Crystal structure of 2-{(E)-[(2-hy-droxy-phen-yl)iminium-yl]meth-yl}-4-methyl-phenolate.


ABSTRACT: The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13?(9)°. Intra-molecular N-H?O hydrogen bond generate S(6) and S(5) loops. In the crystal, mol-ecules are connected by O-H?O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

SUBMITTER: Shalini S 

PROVIDER: S-EPMC4420074 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

altmetric image

Publications

Crystal structure of 2-{(E)-[(2-hy-droxy-phen-yl)iminium-yl]meth-yl}-4-methyl-phenolate.

Shalini Suresh S   Girija C R CR   Jotani Mukesh M MM   Sathish C D CD   Venkatesha T V TV  

Acta crystallographica. Section E, Crystallographic communications 20150409 Pt 5


The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intra-molecular N-H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, mol-ecules are connected by O-H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction. ...[more]

Similar Datasets

| S-EPMC3393892 | biostudies-literature
| S-EPMC4438828 | biostudies-literature
| S-EPMC3435650 | biostudies-literature
| S-EPMC4645060 | biostudies-literature
| S-EPMC3006709 | biostudies-literature
| S-EPMC4719913 | biostudies-literature
| S-EPMC4645002 | biostudies-literature
| S-EPMC4647401 | biostudies-literature
| S-EPMC3379223 | biostudies-literature
| S-EPMC4647357 | biostudies-literature