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Crystal structure of 2-{(E)-[(2-hy-droxy-phen-yl)iminium-yl]meth-yl}-4-methyl-phenolate.

ABSTRACT: The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13?(9)°. Intra-molecular N-H?O hydrogen bond generate S(6) and S(5) loops. In the crystal, mol-ecules are connected by O-H?O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

SUBMITTER: Shalini S

PROVIDER: S-EPMC4420074 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Crystal structure of 2-{(E)-[(2-hy-droxy-phen-yl)iminium-yl]meth-yl}-4-methyl-phenolate.

Shalini Suresh S Girija C R CR Jotani Mukesh M MM Sathish C D CD Venkatesha T V TV

Acta crystallographica. Section E, Crystallographic communications 20150409 Pt 5

The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intra-molecular N-H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, mol-ecules are connected by O-H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction. ...[more]

PMID: 25995908

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