Ontology highlight
ABSTRACT:
SUBMITTER: Merola JS
PROVIDER: S-EPMC4420101 | biostudies-literature | 2015 May
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20150422 Pt 5
The reaction between IrCl3·xH2O in methanol led to the formation of small amounts of the title compound, [Ir2Cl6(CH3OH)4]·2H2O, which consists of two IrCl4O2 octa-hedra sharing an edge via chloride bridges. The mol-ecule lies across an inversion center. Each octa-hedron can be envisioned as being comprised of four chloride ligands in the equatorial plane with methanol ligands in the axial positions. A lattice water mol-ecule is strongly hydrogen-bonded to the coordinating methanol ligands and we ...[more]