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Entrapment of metal clusters in metal-organic framework channels by extended hooks anchored at open metal sites.

ABSTRACT: Reported here are the new concept of utilizing open metal sites (OMSs) for architectural pore design and its practical implementation. Specifically, it is shown here that OMSs can be used to run extended hooks (isonicotinates in this work) from the framework walls to the channel centers to effect the capture of single metal ions or clusters, with the concurrent partitioning of the large channel spaces into multiple domains, alteration of the host-guest charge relationship and associated guest-exchange properties, and transfer of OMSs from the walls to the channel centers. The concept of the extended hook, demonstrated here in the multicomponent dual-metal and dual-ligand system, should be generally applicable to a range of framework types.

SUBMITTER: Zheng ST

PROVIDER: S-EPMC4425563 | biostudies-literature | 2013 Jul

REPOSITORIES: biostudies-literature

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Entrapment of metal clusters in metal-organic framework channels by extended hooks anchored at open metal sites.

Zheng Shou-Tian ST Zhao Xiang X Lau Samuel S Fuhr Addis A Feng Pingyun P Bu Xianhui X

Journal of the American Chemical Society 20130705 28

Reported here are the new concept of utilizing open metal sites (OMSs) for architectural pore design and its practical implementation. Specifically, it is shown here that OMSs can be used to run extended hooks (isonicotinates in this work) from the framework walls to the channel centers to effect the capture of single metal ions or clusters, with the concurrent partitioning of the large channel spaces into multiple domains, alteration of the host-guest charge relationship and associated guest-ex ...[more]

PMID: 23826752

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