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Development of composite inorganic building blocks for MOFs.

ABSTRACT: A general direction for diversifying metal-organic frameworks (MOFs) is demonstrated by the synthesis of composite inorganic clusters between indium and s-, d-, and f-block elements. These previously unknown heterometallic clusters, with various nuclearity, geometry, charge, and metal-to-metal ratios, significantly expand the pool of inorganic building blocks that are highly effective for the construction of porous MOFs with high gas uptake capacity.

SUBMITTER: Zheng ST

PROVIDER: S-EPMC4425565 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Development of composite inorganic building blocks for MOFs.

Zheng Shou-Tian ST Wu Tao T Chou Chengtsung C Fuhr Addis A Feng Pingyun P Bu Xianhui X

Journal of the American Chemical Society 20120227 10

A general direction for diversifying metal-organic frameworks (MOFs) is demonstrated by the synthesis of composite inorganic clusters between indium and s-, d-, and f-block elements. These previously unknown heterometallic clusters, with various nuclearity, geometry, charge, and metal-to-metal ratios, significantly expand the pool of inorganic building blocks that are highly effective for the construction of porous MOFs with high gas uptake capacity. ...[more]

PMID: 22369434

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