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Crystal structure of 3-(3,4-di-methyl-anilino)-2-benzo-furan-1(3H)-one.

ABSTRACT: In the title compound, C16H15NO2, the 2-benzo-furan-1(3H)-one and 3,4-di-methyl-aniline fragments are oriented with a dihedral angle of 89.12?(5)°. N-H?O hydrogen-bond inter-actions join mol-ecules into C(6) chains propagating along the a axis. In addition, there are ?-? stacking inter-actions between the 2-benzo-furan-one benzene rings [centroid-centroid dis-tance = 3.7870?(13)?Å] and C-H?? inter-actions between one of the methyl groups and the 3,4-di-methyl-aniline benzene ring.

SUBMITTER: Salim M

PROVIDER: S-EPMC4459309 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of 3-(3,4-di-methyl-anilino)-2-benzo-furan-1(3H)-one.

Salim Muhammad M Tahir Muhammad Nawaz MN Shahid Muhammad M Munawar Munawar Ali MA

Acta crystallographica. Section E, Crystallographic communications 20150520 Pt 6

In the title compound, C16H15NO2, the 2-benzo-furan-1(3H)-one and 3,4-di-methyl-aniline fragments are oriented with a dihedral angle of 89.12 (5)°. N-H⋯O hydrogen-bond inter-actions join mol-ecules into C(6) chains propagating along the a axis. In addition, there are π-π stacking inter-actions between the 2-benzo-furan-one benzene rings [centroid-centroid dis-tance = 3.7870 (13) Å] and C-H⋯π inter-actions between one of the methyl groups and the 3,4-di-methyl-aniline benzene ring. ...[more]

PMID: 26090197

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