Ontology highlight
ABSTRACT:
SUBMITTER: Luo J
PROVIDER: S-EPMC4459349 | biostudies-literature | 2015 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20150523 Pt 6
The structures of two mononuclear transition-metal complexes with tri-cyano-methanide (tcm(-)) and 1,4,7,10-tetra-aza-cyclo-dodecane (cyclen) ligands, [Ni(C4N3)2(C8H20N4)], (I), and [Cu(C4N3)(C8H20N4)](C4N3), (II), are reported. In the neutral complex (I), the nickel cation is coordinated by one cyclen ligand and two monodentate N-bound tcm(-) anions in a distorted octa-hedral geometry. The tcm(-) ligands are mutually cis. The Cu(II) atom in (II) displays a distorted tetra-gonal-pyramidal geomet ...[more]