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Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator.

ABSTRACT: An organogelator was produced and identified from a dynamic imine system, resolved and amplified by selective gelation. The formation of the organogel was monitored in situ by (1)H NMR, showing the existence of multiple reversible reactions operating simultaneously, and the redistribution of the involved species during gelation. The formed organogelator proved effective with a range of organic solvents, including DMSO, toluene, and longer, linear alcohols.

SUBMITTER: Hu L

PROVIDER: S-EPMC4462186 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Gelation-driven Dynamic Systemic Resolution: in situ Generation and Self-Selection of an Organogelator.

Hu Lei L Zhang Yang Y Ramström Olof O

Scientific reports 20150616

An organogelator was produced and identified from a dynamic imine system, resolved and amplified by selective gelation. The formation of the organogel was monitored in situ by (1)H NMR, showing the existence of multiple reversible reactions operating simultaneously, and the redistribution of the involved species during gelation. The formed organogelator proved effective with a range of organic solvents, including DMSO, toluene, and longer, linear alcohols. ...[more]

PMID: 26062041

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