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Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers.

ABSTRACT: Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

SUBMITTER: Hill LR

PROVIDER: S-EPMC4498016 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers.

Hill Leila R LR Sørensen Thomas Just TJ Blackburn Octavia A OA Brown Asha A Beer Paul D PD Faulkner Stephen S

Dalton transactions (Cambridge, England : 2003) 20130101 1

Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated. ...[more]

PMID: 23108073

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