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Palladium-catalyzed direct C-H functionalization of benzoquinone.


ABSTRACT: A direct Pd-catalyzed C-H functionalization of benzoquinone (BQ) can be controlled to give either mono- or disubstituted BQ, including the installation of two different groups in a one-pot procedure. BQ can now be directly functionalized with aryl, heteroaryl, cycloalkyl, and cycloalkene groups and, moreover, the reaction is conducted in environmentally benign water or acetone as solvents.

SUBMITTER: Walker SE 

PROVIDER: S-EPMC4502976 | biostudies-literature |

REPOSITORIES: biostudies-literature

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