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Crystal structure of 2-(4-tert-butyl-phen-yl)-3-hydroxy-4H-chromen-4-one.

ABSTRACT: Yellow-green fluorescent crystals of the title compound, C19H18O3, were obtained by the reaction of hy-droxy-aceto-phenone and 4-tert-butyl-benzaldehyde with hydrogen peroxide as oxidant. The plane of the benzene ring is slightly twisted to the mean plane of the 4H-chromene-4-one moiety (r.m.s. deviation = 0.0191 Å) by 10.53 (8)°. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen bonds, forming inversion dimers with an R 2 (2)(10) ring motif. The dimers are linked via C-H⋯π inter-actions, forming sheets parallel to (10-1).

SUBMITTER: Narita F

PROVIDER: S-EPMC4518945 | biostudies-literature | 2015 Jul

REPOSITORIES: biostudies-literature

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Crystal structure of 2-(4-tert-butyl-phen-yl)-3-hydroxy-4H-chromen-4-one.

Narita Fuka F Takura Akihiro A Fujihara Takashi T

Acta crystallographica. Section E, Crystallographic communications 20150624 Pt 7

Yellow-green fluorescent crystals of the title compound, C19H18O3, were obtained by the reaction of hy-droxy-aceto-phenone and 4-tert-butyl-benzaldehyde with hydrogen peroxide as oxidant. The plane of the benzene ring is slightly twisted to the mean plane of the 4H-chromene-4-one moiety (r.m.s. deviation = 0.0191 Å) by 10.53 (8)°. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen bonds, forming inversion dimers with an R 2 (2)(10) ring motif. The dimers are linked via C-H⋯π inter- ...[more]

PMID: 26279877

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