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Probing Cu(I) in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy.

ABSTRACT: Metal-to-ligand charge transfer excitations in Cu(I) X-ray absorption spectra are introduced as spectroscopic handles for the characterization of species in homogeneous catalytic reaction mixtures. Analysis is supported by correlation of a spectral library to calculations and to complementary spectroscopic parameters.

SUBMITTER: Walroth RC 

PROVIDER: S-EPMC4540364 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Probing Cu(I) in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy.

Walroth Richard C RC   Uebler Jacob W H JW   Lancaster Kyle M KM  

Chemical communications (Cambridge, England) 20150601 48

Metal-to-ligand charge transfer excitations in Cu(I) X-ray absorption spectra are introduced as spectroscopic handles for the characterization of species in homogeneous catalytic reaction mixtures. Analysis is supported by correlation of a spectral library to calculations and to complementary spectroscopic parameters. ...[more]

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