Ontology highlight
ABSTRACT:
SUBMITTER: Funwie NL
PROVIDER: S-EPMC4555389 | biostudies-literature | 2015 Sep
REPOSITORIES: biostudies-literature
Funwie Neil L NL Cain Amy N AN Fanning Brian Z BZ Hageman Serena A SA Mullens Malorie M Roberts Travis K TK Turner Daniel J DJ Valdez Cammi N CN Vaughan Robert W RW Ermias Henok G HG Silversides Jon D JD Archibald Stephen J SJ Hubin Timothy J TJ Prior Timothy J TJ
Acta crystallographica. Section E, Crystallographic communications 20150826 Pt 9
The title compound, [FeCl2(C14H30N4)]PF6, contains Fe(3+) coordinated by the four nitro-gen atoms of an ethyl-ene cross-bridged cyclam macrocycle and two cis chloride ligands in a distorted octa-hedral environment. In contrast to other similar compounds this is a monomer. Inter-molecular C-H⋯Cl inter-actions exist in the structure between the complex ions. Comparison with the mononuclear Fe(2+) complex of the same ligand shows that the smaller Fe(3+) ion is more fully engulfed by the cavity of t ...[more]