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Crystal structure of 2,2'-bis-[(2-chloro-benz-yl)-oxy]-1,1'-bi-naphthalene.

ABSTRACT: In the title binaphthyl compound, C34H24Cl2O2, the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035?Å) is 76.33?(8)°. The chloro-phenyl rings make dihedral angles of 58.15?(12) and 76.21?(13)° with the naphthyl ring to which they are linked. The dihedral angle between the planes of the two chloro-phenyl rings is 27.66?(16)°. In the crystal, C-H?O hydrogen bonds link mol-ecules into chains propagating along [1-10]. The chains are linked by C-H?? inter-actions, forming a three-dimensional framework.

SUBMITTER: Raja R

PROVIDER: S-EPMC4555433 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of 2,2'-bis-[(2-chloro-benz-yl)-oxy]-1,1'-bi-naphthalene.

Raja Rajamani R Jayanthi Mani M Rajakumar Perumal P SubbiahPandi A A

Acta crystallographica. Section E, Crystallographic communications 20150806 Pt 9

In the title binaphthyl compound, C34H24Cl2O2, the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035 Å) is 76.33 (8)°. The chloro-phenyl rings make dihedral angles of 58.15 (12) and 76.21 (13)° with the naphthyl ring to which they are linked. The dihedral angle between the planes of the two chloro-phenyl rings is 27.66 (16)°. In the crystal, C-H⋯O hydrogen bonds link mol-ecules into chains propagating along [1-10]. The chains are linked by C-H⋯π inter-acti ...[more]

PMID: 26396878

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