Unknown

Dataset Information

0

Crystal structure of 2,2'-bis-[(2-chloro-benz-yl)-oxy]-1,1'-bi-naphthalene.


ABSTRACT: In the title binaphthyl compound, C34H24Cl2O2, the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035?Å) is 76.33?(8)°. The chloro-phenyl rings make dihedral angles of 58.15?(12) and 76.21?(13)° with the naphthyl ring to which they are linked. The dihedral angle between the planes of the two chloro-phenyl rings is 27.66?(16)°. In the crystal, C-H?O hydrogen bonds link mol-ecules into chains propagating along [1-10]. The chains are linked by C-H?? inter-actions, forming a three-dimensional framework.

SUBMITTER: Raja R 

PROVIDER: S-EPMC4555433 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

altmetric image

Publications

Crystal structure of 2,2'-bis-[(2-chloro-benz-yl)-oxy]-1,1'-bi-naphthalene.

Raja Rajamani R   Jayanthi Mani M   Rajakumar Perumal P   SubbiahPandi A A  

Acta crystallographica. Section E, Crystallographic communications 20150806 Pt 9


In the title binaphthyl compound, C34H24Cl2O2, the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035 Å) is 76.33 (8)°. The chloro-phenyl rings make dihedral angles of 58.15 (12) and 76.21 (13)° with the naphthyl ring to which they are linked. The dihedral angle between the planes of the two chloro-phenyl rings is 27.66 (16)°. In the crystal, C-H⋯O hydrogen bonds link mol-ecules into chains propagating along [1-10]. The chains are linked by C-H⋯π inter-acti  ...[more]

Similar Datasets

| S-EPMC3344493 | biostudies-literature
| S-EPMC2961794 | biostudies-literature
| S-EPMC3998594 | biostudies-literature
| S-EPMC2959541 | biostudies-literature
| S-EPMC10439419 | biostudies-literature
| S-EPMC2960828 | biostudies-other
| S-EPMC3201419 | biostudies-literature
| S-EPMC3414275 | biostudies-literature
| S-EPMC3685066 | biostudies-literature
| S-EPMC3239092 | biostudies-literature