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Crystal structure of (ferrocenylmeth-yl)di-methyl-ammonium hydrogen oxalate.

ABSTRACT: The crystal structure of the title salt, [Fe(C5H5)(C8H13N)](HC2O4), consists of discrete (ferrocenylmeth-yl)di-methyl-ammonium cations and hydrogen oxalate anions. The anions are connected through a strong O-H?O hydrogen bond, forming linear chains running parallel to [100]. The cations are linked to the anions through bifurcated N-H?(O,O') hydrogen bonds. Weak C-H?? inter-actions between neighbouring ferrocenyl moieties are also observed.

SUBMITTER: Ndiaye M

PROVIDER: S-EPMC4571364 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of (ferrocenylmeth-yl)di-methyl-ammonium hydrogen oxalate.

Ndiaye Mamadou M Samb Abdoulaye A Diop Libasse L Maris Thierry T

Acta crystallographica. Section E, Crystallographic communications 20150717 Pt 8

The crystal structure of the title salt, [Fe(C5H5)(C8H13N)](HC2O4), consists of discrete (ferrocenylmeth-yl)di-methyl-ammonium cations and hydrogen oxalate anions. The anions are connected through a strong O-H⋯O hydrogen bond, forming linear chains running parallel to [100]. The cations are linked to the anions through bifurcated N-H⋯(O,O') hydrogen bonds. Weak C-H⋯π inter-actions between neighbouring ferrocenyl moieties are also observed. ...[more]

PMID: 26396763

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Crystal structure of di-methyl-ammonium hydrogen oxalate hemi(oxalic acid).

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(Ferrocenylmeth-yl)dimethyl-ammonium bromide.

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(Di-methyl-phosphor-yl)methanaminium hydrogen oxalate-oxalic acid (2/1).

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Hybrid organic-inorganic crystal structure of 4-(di-methyl-amino)-pyridinium di-methyl-ammonium tetra-chlorido-lead(II).

Project description:The title compound, (C2H8N)(C7H11N2)[PbCl4], is a hybrid organic-inorganic material. It crystallizes in the space group C2/c and contains one half of a mol-ecule of lead chloride, 4-(di-methyl-amino)-pyridinium, and di-methyl-ammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(di-methyl-amino)-pyridinium and di-methyl-ammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and di-methyl-benzene-1,4-diaminium.

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Crystal structure of bis-(allyl-ammonium) oxalate.

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