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Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo-di-thio-ate.

ABSTRACT: In the title compound, C17H19NO2S2, the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.0383?(28)?Å, and the piperidine ring adopts a chair conformation. The 2H-chromene ring makes dihedral angles of 32.89?(16) and 67.33?(8)°, respectively, with the mean planes of the piperidine ring and the carbodi-thio-ate group. In the crystal, C-H?O and weak C-H?S hydrogen bonds link the mol-ecules into chains along [001]. The crystal structure also features C-H?? and ?-? inter-actions, with a centroid-centroid distance of 3.7097?(17)?Å.

SUBMITTER: Roopashree KR

PROVIDER: S-EPMC4571421 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo-di-thio-ate.

Roopashree K R KR Meenakshi T G TG Kumar K Mahesh KM Kotresh O O Devarajegowda H C HC

Acta crystallographica. Section E, Crystallographic communications 20150729 Pt 8

In the title compound, C17H19NO2S2, the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.0383 (28) Å, and the piperidine ring adopts a chair conformation. The 2H-chromene ring makes dihedral angles of 32.89 (16) and 67.33 (8)°, respectively, with the mean planes of the piperidine ring and the carbodi-thio-ate group. In the crystal, C-H⋯O and weak C-H⋯S hydrogen bonds link the mol-ecules into chains along [001]. The crystal structure also features C-H⋯π and π-π inter-action ...[more]

PMID: 26396821

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