Ontology highlight
ABSTRACT:
SUBMITTER: Navarro-Vazquez A
PROVIDER: S-EPMC4578395 | biostudies-literature | 2015
REPOSITORIES: biostudies-literature
Beilstein journal of organic chemistry 20150818
The base-catalyzed isomerization of N-propargylamides or carbamates may furnish N-allenyl compounds (allenamides/allencarbamates) or further evolve to N-alkynyl compounds (ynamides or yncarbamates). The particular fate of this reaction varies from experiment to experiment and there is no clear rule for predicting the reaction outcome for a particular structure. With the support of ab initio and DFT computations, this work shows that observed results can be explained by assuming an exchange equil ...[more]