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Conversion of Saccharides into Formic Acid using Hydrogen Peroxide and a Recyclable Palladium(II) Catalyst in Aqueous Alkaline Media at Ambient Temperatures.

ABSTRACT: We have developed an effective method that converts a variety of mono- and disaccharides into formic acid predominantly. Our recyclable NHC-amidate palladium(II) catalyst facilitated oxidative degradation of carbohydrates without using excess oxidant. Stoichiometric amounts of hydrogen peroxide and sodium hydroxide were employed at ambient temperatures.

SUBMITTER: Zargari N

PROVIDER: S-EPMC4584152 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Conversion of Saccharides into Formic Acid using Hydrogen Peroxide and a Recyclable Palladium(II) Catalyst in Aqueous Alkaline Media at Ambient Temperatures.

Zargari N N Kim Y Y Jung K W KW

Green chemistry : an international journal and green chemistry resource : GC 20150303 5

We have developed an effective method that converts a variety of mono- and disaccharides into formic acid predominantly. Our recyclable NHC-amidate palladium(II) catalyst facilitated oxidative degradation of carbohydrates without using excess oxidant. Stoichiometric amounts of hydrogen peroxide and sodium hydroxide were employed at ambient temperatures. ...[more]

PMID: 26421000

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