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Large Scale Synthesis and Light Emitting Fibers of Tailor-Made Graphene Quantum Dots.

ABSTRACT: Graphene oxide (GO), which is an oxidized form of graphene, has a mixed structure consisting of graphitic crystallites of sp(2) hybridized carbon and amorphous regions. In this work, we present a straightforward route for preparing graphene-based quantum dots (GQDs) by extraction of the crystallites from the amorphous matrix of the GO sheets. GQDs with controlled functionality are readily prepared by varying the reaction temperature, which results in precise tunability of their optical properties. Here, it was concluded that the tunable optical properties of GQDs are a result of the different fraction of chemical functionalities present. The synthesis approach presented in this paper provides an efficient strategy for achieving large-scale production and long-time optical stability of the GQDs, and the hybrid assembly of GQD and polymer has potential applications as photoluminescent fibers or films.

SUBMITTER: Park H

PROVIDER: S-EPMC4585659 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

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Large Scale Synthesis and Light Emitting Fibers of Tailor-Made Graphene Quantum Dots.

Park Hun H Noh Sung Hyun SH Lee Ji Hye JH Lee Won Jun WJ Jaung Jae Yun JY Lee Seung Geol SG Han Tae Hee TH

Scientific reports 20150918

Graphene oxide (GO), which is an oxidized form of graphene, has a mixed structure consisting of graphitic crystallites of sp(2) hybridized carbon and amorphous regions. In this work, we present a straightforward route for preparing graphene-based quantum dots (GQDs) by extraction of the crystallites from the amorphous matrix of the GO sheets. GQDs with controlled functionality are readily prepared by varying the reaction temperature, which results in precise tunability of their optical propertie ...[more]

PMID: 26383257

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