Browse
Submit Data
Databases
API
Help

Dataset Information

37 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Three-Dimensional (3D) Bicontinuous Hierarchically Porous Mn2O3 Single Crystals for High Performance Lithium-Ion Batteries.

ABSTRACT: Bicontinuous hierarchically porous Mn2O3 single crystals (BHP-Mn2O3-SCs) with uniform parallelepiped geometry and tunable sizes have been synthesized and used as anode materials for lithium-ion batteries (LIBs). The monodispersed BHP-Mn2O3-SCs exhibit high specific surface area and three dimensional interconnected bimodal mesoporosity throughout the entire crystal. Such hierarchical interpenetrating porous framework can not only provide a large number of active sites for Li ion insertion, but also good conductivity and short diffusion length for Li ions, leading to a high lithium storage capacity and enhanced rate capability. Furthermore, owing to their specific porosity, these BHP-Mn2O3-SCs as anode materials can accommodate the volume expansion/contraction that occurs with lithium insertion/extraction during discharge/charge processes, resulting in their good cycling performance. Our synthesized BHP-Mn2O3-SCs with a size of ~700 nm display the best electrochemical performance, with a large reversible capacity (845 mA h g(-1) at 100 mA g(-1) after 50 cycles), high coulombic efficiency (>95%), excellent cycling stability and superior rate capability (410 mA h g(-1) at 1 Ag(-1)). These values are among the highest reported for Mn2O3-based bulk solids and nanostructures. Also, electrochemical impedance spectroscopy study demonstrates that the BHP-Mn2O3-SCs are suitable for charge transfer at the electrode/electrolyte interface.

SUBMITTER: Huang SZ

PROVIDER: S-EPMC4593967 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Inward lithium-ion breathing of hierarchically porous silicon anodes.

Project description:Silicon has been identified as a highly promising anode for next-generation lithium-ion batteries (LIBs). The key challenge for Si anodes is large volume change during the lithiation/delithiation cycle that results in chemomechanical degradation and subsequent rapid capacity fading. Here we report a novel fabrication method for hierarchically porous Si nanospheres (hp-SiNSs), which consist of a porous shell and a hollow core. On charge/discharge cycling, the hp-SiNSs accommodate the volume change through reversible inward Li breathing with negligible particle-level outward expansion. Our mechanics analysis revealed that such inward expansion is enabled by the much stiffer lithiated layer than the unlithiated porous layer. LIBs assembled with the hp-SiNSs exhibit high capacity, high power and long cycle life, which is superior to the current commercial Si-based anode materials. The low-cost synthesis approach provides a new avenue for the rational design of hierarchically porous structures with unique materials properties.

| S-EPMC4667626 | biostudies-literature

Dual-Templating Approaches to Soybeans Milk-Derived Hierarchically Porous Heteroatom-Doped Carbon Materials for Lithium-Ion Batteries.

Project description:Biomass derived carbon materials are widely available, cheap and abundant resources. The application of these materials as electrodes for rechargeable batteries shows great promise. To further explore their applications in energy storage fields, the structural design of these materials has been investigated. Hierarchical porous heteroatom-doped carbon materials (HPHCs) with open three-dimensional (3D) nanostructure have been considered as highly efficient energy storage materials. In this work, biomass soybean milk is chosen as the precursor to construct N, O co-doped interconnected 3D porous carbon framework via two approaches by using soluble salts (NaCl/Na2CO3 and ZnCl2/Mg5(OH)2(CO3)4, respectively) as hard templates. The electrochemical results reveal that these structures were able to provide a stable cycling performance (710?mAh???g-1 at 0.1?A???g-1 after 300 cycles for HPHC-a, and 610?mAh???g-1 at 0.1?A???g-1 after 200 cycles for HPHC-b) in Li-ion battery and Na-ion storage (210?mAh???g-1 at 0.1?A???g-1 after 900 cycles for HPHC-a) as anodes materials, respectively. Further comparative studies showed that these improvements in HPHC-a performance were mainly due to the honeycomb-like structure containing graphene-like nanosheets and high nitrogen content in the porous structures. This work provides new approaches for the preparation of hierarchically structured heteroatom-doped carbon materials by pyrolysis of other biomass precursors and promotes the applications of carbon materials in energy storage fields.

| S-EPMC7216455 | biostudies-literature

Bio-Derived, Binderless, Hierarchically Porous Carbon Anodes for Li-ion Batteries.

Project description:Here we explore the electrochemical performance of pyrolyzed skins from the species A. bisporus, also known as the Portobello mushroom, as free-standing, binder-free, and current collector-free Li-ion battery anodes. At temperatures above 900 °C, the biomass-derived carbon nanoribbon-like architectures undergo unique processes to become hierarchically porous. During heat-treatment, the oxygen and heteroatom-rich organics and potassium compounds naturally present in the mushroom skins play a mutual role in creating inner void spaces throughout the resulting carbon nanoribbons, which is a process analogous to KOH-activation of carbon materials seen in literature. The pores formed in the pyrolytic carbon nanoribbons range in size from sub-nanometer to tens of nanometers, making the nanoribbons micro, meso, and macroporous. Detailed studies were conducted on the carbon nanoribbons using SEM and TEM to study morphology, as well as XRD and EDS to study composition. The self-supporting nanoribbon anodes demonstrate significant capacity increase as they undergo additional charge/discharge cycles. After a pyrolysis temperature of 1100 °C, the pristine anodes achieve over 260 mAh/g after 700 cycles and a Coulombic efficiency of 101.1%, without the use of harmful solvents or chemical activation agents.

| S-EPMC4586494 | biostudies-other

One-Dimensional Porous Silicon Nanowires with Large Surface Area for Fast Charge⁻Discharge Lithium-Ion Batteries.

Project description:In this study, one-dimensional porous silicon nanowire (1D⁻PSiNW) arrays were fabricated by one-step metal-assisted chemical etching (MACE) to etch phosphorus-doped silicon wafers. The as-prepared mesoporous 1D⁻PSiNW arrays here had especially high specific surface areas of 323.47 m²·g-1 and were applied as anodes to achieve fast charge⁻discharge performance for lithium ion batteries (LIBs). The 1D⁻PSiNWs anodes with feature size of ~7 nm exhibited reversible specific capacity of 2061.1 mAh·g-1 after 1000 cycles at a high current density of 1.5 A·g-1. Moreover, under the ultrafast charge⁻discharge current rate of 16.0 A·g-1, the 1D⁻PSiNWs anodes still maintained 586.7 mAh·g-1 capacity even after 5000 cycles. This nanoporous 1D⁻PSiNW with high surface area is a potential anode candidate for the ultrafast charge⁻discharge in LIBs with high specific capacity and superior cycling performance.

| S-EPMC5977299 | biostudies-literature

Delocalized Lithium Ion Flux by Solid-State Electrolyte Composites Coupled with 3D Porous Nanostructures for Highly Stable Lithium Metal Batteries.

Project description:This work investigates the root cause of failure with the ultimate anode, Li metal, when employing conventional/composite separators and/or porous anodes. Then a feasible route of utilizing Li metal is presented. Our operando and microscopy studies have unveiled that Li+ flux passing through the conventional separator is not uniform, resulting in preferential Li plating/stripping. Porous anodes alone are subject to clogging with moderate- or high-loading cathodes. Here we discovered it is necessary to seek synergy from our separator and anode pair to deliver delocalized Li+ to the anode and then uniformly plate Li metal over the large surface areas of the porous anode. Our polymer composite separator containing a solid-state electrolyte (SE) can provide numerous Li+ passages through the percolated SE and pore networks. Our finite element analysis and comparative tests disclosed the synergy between the homogeneous Li+ flux and current density reduction on the anode. Our composite separators have induced compact and uniform Li plating with robust inorganic-rich solid electrolyte interphase layers. The porous anode decreased the nucleation overpotential and interfacial contact impedance during Li plating. Full cell tests with LiFePO4 and Li[Ni0.8Mn0.1Co0.1]O2 (NMC811) exhibited remarkable cycling behaviors: ∼80% capacity retention at the 750th and 235th cycle, respectively. A high-loading NMC811 (4 mAh cm-2) full cell displayed maximum cell-level energy densities of 334 Wh kg-1 and 783 Wh L-1. This work proposes a solution for raising energy density by adopting Li metal, which could be a viable option considering only incremental advancement in conventional cathodes lately.

| S-EPMC10863402 | biostudies-literature

Hierarchically mesoporous CuO/carbon nanofiber coaxial shell-core nanowires for lithium ion batteries.

Project description:Hierarchically mesoporous CuO/carbon nanofiber coaxial shell-core nanowires (CuO/CNF) as anodes for lithium ion batteries were prepared by coating the Cu2(NO3)(OH)3 on the surface of conductive and elastic CNF via electrophoretic deposition (EPD), followed by thermal treatment in air. The CuO shell stacked with nanoparticles grows radially toward the CNF core, which forms hierarchically mesoporous three-dimensional (3D) coaxial shell-core structure with abundant inner spaces in nanoparticle-stacked CuO shell. The CuO shells with abundant inner spaces on the surface of CNF and high conductivity of 1D CNF increase mainly electrochemical rate capability. The CNF core with elasticity plays an important role in strongly suppressing radial volume expansion by inelastic CuO shell by offering the buffering effect. The CuO/CNF nanowires deliver an initial capacity of 1150 mAh g(-1) at 100 mA g(-1) and maintain a high reversible capacity of 772 mAh g(-1) without showing obvious decay after 50 cycles.

| S-EPMC4421830 | biostudies-other

Fabrication of hierarchically porous TiO<sub>2</sub> nanofibers by microemulsion electrospinning and their application as anode material for lithium-ion batteries.

Project description:Titanium dioxide (TiO2) nanofibers have been widely applied in various fields including photocatalysis, energy storage and solar cells due to the advantages of low cost, high abundance and nontoxicity. However, the low conductivity of ions and bulk electrons hinder its rapid development in lithium-ion batteries (LIB). In order to improve the electrochemical performances of TiO2 nanomaterials as anode for LIB, hierarchically porous TiO2 nanofibers with different tetrabutyl titanate (TBT)/paraffin oil ratios were prepared as anode for LIB via a versatile single-nozzle microemulsion electrospinning (ME-ES) method followed by calcining. The experimental results indicated that TiO2 nanofibers with the higher TBT/paraffin oil ratio demonstrated more axially aligned channels and a larger specific surface area. Furthermore, they presented superior lithium-ion storage properties in terms of specific capacity, rate capability and cycling performance compared with solid TiO2 nanofibers for LIB. The initial discharge and charge capacity of porous TiO2 nanofibers with a TBT/paraffin oil ratio of 2.25 reached up to 634.72 and 390.42 mAh·g-1, thus resulting in a coulombic efficiency of 61.51%; and the discharge capacity maintained 264.56 mAh·g-1 after 100 cycles, which was much higher than that of solid TiO2 nanofibers. TiO2 nanofibers with TBT/paraffin oil ratio of 2.25 still obtained a high reversible capacity of 204.53 mAh·g-1 when current density returned back to 40 mA·g-1 after 60 cycles at increasing stepwise current density from 40 mA·g-1 to 800 mA·g-1. Herein, hierarchically porous TiO2 nanofibers have the potential to be applied as anode for lithium-ion batteries in practical applications.

| S-EPMC5496575 | biostudies-literature

Nitrogen-doped carbon paper with 3D porous structure as a flexible free-standing anode for lithium-ion batteries.

Project description:In this paper, a novel nitrogen-doped carbon paper (NCP) with both highly dense three-dimensional cellular structure and excellent bending flexibility is fabricated by pyrolyzing a melamine foam under compression. When serving as a free-standing anode for lithium-ion batteries, the NCP electrode delivers a reversible capacity up to 329.8?mA?h g-1 after 200 cycles at 0.5?A?g-1 (1.34?C) and 126.5?mA?h g-1 after 500 cycles at 8.0?A?g-1 (21.5?C). Such electrochemical performance is much higher than those of the counterparts prepared by pyrolysis without compression and can be mainly attributed to (a) the 3D highly dense interconnected carbon network with numerous junctions which can facilitate the efficient electron transfer and provide short transportation paths for lithium ions; and (b) the excellent mechanical flexibility and self-standing capability which exempt the use of binder, conductive additive and current collector. The NCP electrode implies a great promise of application in the high-performance Li-ion batteries for the flexible and wearable electronics.

| S-EPMC5552696 | biostudies-literature

Monodisperse porous silicon spheres as anode materials for lithium ion batteries.

Project description:Highly monodisperse porous silicon nanospheres (MPSSs) are synthesized via a simple and scalable hydrolysis process with subsequent surface-protected magnesiothermic reduction. The spherical nature of the MPSSs allows for a homogenous stress-strain distribution within the structure during lithiation and delithiation, which dramatically improves the electrochemical stability. To fully extract the real performance of the MPSSs, carbon nanotubes (CNTs) were added to enhance the electronic conductivity within the composite electrode structure, which has been verified to be an effective way to improve the rate and cycling performance of anodes based on nano-Si. The Li-ion battery (LIB) anodes based on MPSSs demonstrate a high reversible capacity of 3105 mAh g(-1). In particular, reversible Li storage capacities above 1500 mAh g(-1) were maintained after 500 cycles at a high rate of C/2. We believe this innovative approach for synthesizing porous Si-based LIB anode materials by using surface-protected magnesiothermic reduction can be readily applied to other types of SiOx nano/microstructures.

| S-EPMC4350083 | biostudies-literature

Hollow porous SiO2 nanocubes towards high-performance anodes for lithium-ion batteries.

Project description:The high theoretical capacity and low discharge potential of silicon have attracted much attention on Si-based anodes. Herein, hollow porous SiO2 nanocubes have been prepared via a two-step hard-template process and evaluated as electrode materials for lithium-ion batteries. The hollow porous SiO2 nanocubes exhibited a reversible capacity of 919 mAhg(-1) over 30 cycles. The reasonable property could be attributed to the unique hollow nanostructure with large volume interior and numerous crevices in the shell, which could accommodate the volume change and alleviate the structural strain during Li ions' insertion and extraction, as well as allow rapid access of Li ions during charge/discharge cycling. It is found that the formation of irreversible or reversible lithium silicates in the anodes determines the capacity of a deep-cycle battery, fast transportation of Li ions in hollow porous SiO2 nanocubes is beneficial to the formation of Li2O and Si, contributing to the high reversible capacity.

| S-EPMC3610094 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data