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Core formation and core composition from coupled geochemical and geophysical constraints.

ABSTRACT: The formation of Earth's core left behind geophysical and geochemical signatures in both the core and mantle that remain to this day. Seismology requires that the core be lighter than pure iron and therefore must contain light elements, and the geochemistry of mantle-derived rocks reveals extensive siderophile element depletion and fractionation. Both features are inherited from metal-silicate differentiation in primitive Earth and depend upon the nature of physiochemical conditions that prevailed during core formation. To date, core formation models have only attempted to address the evolution of core and mantle compositional signatures separately, rather than seeking a joint solution. Here we combine experimental petrology, geochemistry, mineral physics and seismology to constrain a range of core formation conditions that satisfy both constraints. We find that core formation occurred in a hot (liquidus) yet moderately deep magma ocean not exceeding 1,800 km depth, under redox conditions more oxidized than present-day Earth. This new scenario, at odds with the current belief that core formation occurred under reducing conditions, proposes that Earth's magma ocean started oxidized and has become reduced through time, by oxygen incorporation into the core. This core formation model produces a core that contains 2.7-5% oxygen along with 2-3.6% silicon, with densities and velocities in accord with radial seismic models, and leaves behind a silicate mantle that matches the observed mantle abundances of nickel, cobalt, chromium, and vanadium.

SUBMITTER: Badro J

PROVIDER: S-EPMC4603515 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Core formation and core composition from coupled geochemical and geophysical constraints.

Badro James J Brodholt John P JP Piet Hélène H Siebert Julien J Ryerson Frederick J FJ

Proceedings of the National Academy of Sciences of the United States of America 20150921 40

The formation of Earth's core left behind geophysical and geochemical signatures in both the core and mantle that remain to this day. Seismology requires that the core be lighter than pure iron and therefore must contain light elements, and the geochemistry of mantle-derived rocks reveals extensive siderophile element depletion and fractionation. Both features are inherited from metal-silicate differentiation in primitive Earth and depend upon the nature of physiochemical conditions that prevail ...[more]

PMID: 26392555

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Project description:The chemical and physical properties of the interiors of terrestrial planets are largely determined during their formation and differentiation. Modeling a planet's formation provides important insights into the properties of its core and mantle, and conversely, knowledge of those properties may constrain formational narratives. Here, we present a multi-stage model of Martian core formation in which we calculate core-mantle equilibration using parameterizations from high pressure-temperature metal-silicate partitioning experiments. We account for changing core-mantle boundary (CMB) conditions, composition-dependent partitioning, and partial equilibration of metal and silicate, and we evolve oxygen fugacity (fO2) self-consistently. The model successfully reproduces published meteorite-based estimates of most elemental abundances in the bulk silicate Mars, which can be used to estimate core formation conditions and core composition. This composition implies that the primordial material that formed Mars was significantly more oxidized (0.9-1.4 log units below the iron-wüstite buffer) than that of the Earth, and that core-mantle equilibration in Mars occurred at 42-60% of the evolving CMB pressure. On average, at least 84% of accreted metal and at least 40% of the mantle were equilibrated in each impact, a significantly higher degree of metal equilibration than previously reported for the Earth. In agreement with previous studies, the modeled Martian core is rich in sulfur (18-19 wt%), with less than one weight percent O and negligible Si. We have used these core and mantle compositions to produce physical models of the present-day Martian interior and evaluate the sensitivity of core radius to crustal thickness, mantle temperature, core composition, core temperature, and density of the core alloy. Trade-offs in how these properties affect observable physical parameters like planetary mass, radius, moment of inertia, and tidal Love number k2 define a range of likely core radii: 1620-1870 km. Seismic velocity profiles for several combinations of model parameters have been used to predict seismic body-wave travel times and planetary normal mode frequencies. These results may be compared to forthcoming Martian seismic data to further constrain core formation conditions and geophysical properties.

Dataset Information

Core formation and core composition from coupled geochemical and geophysical constraints.

Publications

Core formation and core composition from coupled geochemical and geophysical constraints.

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