Unknown

Dataset Information

0

Manganese-Mediated Coupling Reaction of Vinylarenes and Aliphatic Alcohols.


ABSTRACT: Alcohols and alkenes are the most abundant and commonly used organic building blocks in the large-scale chemical synthesis. Herein, this is the first time to report a novel and operationally simple coupling reaction of vinylarenes and aliphatic alcohols catalyzed by manganese in the presence of TBHP (tert-butyl hydroperoxide). This coupling reaction provides the oxyalkylated products of vinylarenes with good regioselectivity and accomplishes with the principles of step-economies. A possible reaction mechanism has also been proposed.

SUBMITTER: Zhang W 

PROVIDER: S-EPMC4607950 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC6648503 | biostudies-literature
| S-EPMC6359925 | biostudies-literature
| S-EPMC7542462 | biostudies-literature
| S-EPMC6844157 | biostudies-literature
| S-EPMC4000167 | biostudies-literature
| S-EPMC6156109 | biostudies-literature
| S-EPMC4153350 | biostudies-literature
| S-EPMC7750973 | biostudies-literature
| S-EPMC6524566 | biostudies-literature
| S-EPMC5729750 | biostudies-literature