Ontology highlight
ABSTRACT:
SUBMITTER: Suess DL
PROVIDER: S-EPMC4618401 | biostudies-literature | 2015 Sep
REPOSITORIES: biostudies-literature
Suess Daniel L M DL Britt R David RD
Catalysis letters 20150730 12
Proton reduction and H<sub>2</sub> oxidation are key elementary reactions for solar fuel production. Hydrogenases interconvert H<sup>+</sup> and H<sub>2</sub> with remarkable efficiency and have therefore received much attention in this context. For [FeFe]-hydrogenases, catalysis occurs at a unique cofactor called the H-cluster. In this article, we discuss ways in which EPR spectroscopy has elucidated aspects of the bioassembly of the H-cluster, with a focus on four case studies: EPR spectroscop ...[more]