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Versatile Molding Process for Tough Cellulose Hydrogel Materials.

ABSTRACT: Shape-persistent and tough cellulose hydrogels were fabricated by a stepwise solvent exchange from a homogeneous ionic liquid solution of cellulose exposure to methanol vapor. The cellulose hydrogels maintain their shapes under changing temperature, pH, and solvents. The micrometer-scale patterns on the mold were precisely transferred onto the surface of cellulose hydrogels. We also succeeded in the spinning of cellulose hydrogel fibers through a dry jet-wet spinning process. The mechanical property of regenerated cellulose fibers improved by the drawing of cellulose hydrogel fibers during the spinning process. This approach for the fabrication of tough cellulose hydrogels is a major advance in the fabrication of cellulose-based structures with defined shapes.

SUBMITTER: Kimura M

PROVIDER: S-EPMC4633679 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Versatile Molding Process for Tough Cellulose Hydrogel Materials.

Kimura Mutsumi M Shinohara Yoshie Y Takizawa Junko J Ren Sixiao S Sagisaka Kento K Lin Yudeng Y Hattori Yoshiyuki Y Hinestroza Juan P JP

Scientific reports 20151105

Shape-persistent and tough cellulose hydrogels were fabricated by a stepwise solvent exchange from a homogeneous ionic liquid solution of cellulose exposure to methanol vapor. The cellulose hydrogels maintain their shapes under changing temperature, pH, and solvents. The micrometer-scale patterns on the mold were precisely transferred onto the surface of cellulose hydrogels. We also succeeded in the spinning of cellulose hydrogel fibers through a dry jet-wet spinning process. The mechanical prop ...[more]

PMID: 26537533

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