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Crystal structure of 2-fluoro-N-(1,3-thia-zol-2-yl)benzamide.

ABSTRACT: In the title compound, C10H7FN2OS, the mean plane of the central amide fragment (r.m.s. deviation = 0.048?Å) makes dihedral angles of 35.28?(8) and 10.14?(12)° with those of the fluoro-benzene and thia-zole rings, respectively. The thia-zole S and amide O atoms lie to the same side of the mol-ecule. In the crystal, pairs of N-H?N hydrogen bonds connect the mol-ecules into inversion dimers with R 2 (2)(8) motifs, and weak C-H?O inter-actions connect the mol-ecules into C(6) [001] chains. Together, the N-H?N and C-H?O hydrogen bonds generate (100) sheets.

SUBMITTER: Moreno-Fuquen R

PROVIDER: S-EPMC4645012 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of 2-fluoro-N-(1,3-thia-zol-2-yl)benzamide.

Moreno-Fuquen Rodolfo R Castillo Juan C JC Becerra Diana D Camargo Hernando H Henao José A JA

Acta crystallographica. Section E, Crystallographic communications 20151024 Pt 11

In the title compound, C10H7FN2OS, the mean plane of the central amide fragment (r.m.s. deviation = 0.048 Å) makes dihedral angles of 35.28 (8) and 10.14 (12)° with those of the fluoro-benzene and thia-zole rings, respectively. The thia-zole S and amide O atoms lie to the same side of the mol-ecule. In the crystal, pairs of N-H⋯N hydrogen bonds connect the mol-ecules into inversion dimers with R 2 (2)(8) motifs, and weak C-H⋯O inter-actions connect the mol-ecules into C(6) [001] chains. Together ...[more]

PMID: 26594578

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