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Crystal structure of 2-(3-nitro-phen-yl)-1,3-thia-zolo[4,5-b]pyridine.

ABSTRACT: In the title compound, C12H7N3O2S, the dihedral angle between the planes of the thia-zolo-pyridine ring system (r.m.s. deviation = 0.005?Å) and the benzene ring is 3.94?(6)°. The nitro group is rotated by 7.6?(2)° from its attached ring. In the crystal, extensive aromatic ?-? stacking [shortest centroid-centroid separation = 3.5295?(9)?Å] links the mol-ecules into (001) sheets.

SUBMITTER: El-Hiti GA

PROVIDER: S-EPMC4645065 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of 2-(3-nitro-phen-yl)-1,3-thia-zolo[4,5-b]pyridine.

El-Hiti Gamal A GA Smith Keith K Hegazy Amany S AS Ajarim Mansour D MD Kariuki Benson M BM

Acta crystallographica. Section E, Crystallographic communications 20151024 Pt 11

In the title compound, C12H7N3O2S, the dihedral angle between the planes of the thia-zolo-pyridine ring system (r.m.s. deviation = 0.005 Å) and the benzene ring is 3.94 (6)°. The nitro group is rotated by 7.6 (2)° from its attached ring. In the crystal, extensive aromatic π-π stacking [shortest centroid-centroid separation = 3.5295 (9) Å] links the mol-ecules into (001) sheets. ...[more]

PMID: 26594575

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Crystal structure of ethyl 4-(2,4-di-chloro-phen-yl)-2-methyl-4H-benzo[4,5]thia-zolo[3,2-a]pyrimidine-3-carboxyl-ate.

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