Crystal structure of 2-[2-(hy-droxy-imino)-1-phenyl-propyl-idene]-N-phen-ylhydrazinecarbo-thio-amide.

ABSTRACT: In the title compound, C16H16N4OS, an intra-molecular C-H?S hydrogen bond is observed. With the exception of the phenyl ring of the phenyl-propyl-idene unit, the remainder of the mol-ecule has an almost planar skeleton with an r.m.s. deviation of 0.121?(5)?Å from the plane through the remaining 16 atoms. In the crystal O-H?N hydrogen bonds are observed between the terminal hy-droxy-imino groups, forming inverson dimers with R 2 (2)(6) graph-set motifs. Additional C-H?N contacts stack the dimers along [100]. While no ?-? inter-actions are present, weak C-H?O and O-H?Cg inter-actions are also observed and help stabilize the crystal packing.

SUBMITTER: Anderson BJ 

PROVIDER: S-EPMC4647349 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature