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Crystal structure of [(2S,3R)-3-hy-droxy-3-phenyl-butan-2-yl]pyrrolidinium chloride.

ABSTRACT: In the title mol-ecular salt, C14H22NO(+)·Cl(-), the pyrrolidinium ring adopts a twisted conformation about one of the N-C bonds. It is oriented at a dihedral angle of 42.0?(1)° with respect to the benzene ring. The torsion angle for the central N-C-C-Car (ar = aromatic) linkage is 163.74?(15)°. In the crystal, the components are linked via N-H?Cl and O-H?Cl hydrogen bonds, forming zigzig chains along the b-axis direction. These chains are connected along the c axis by very weak C-H?? inter-actions, forming a two-dimensional supra-molecular network.

SUBMITTER: Kandhaswamy A

PROVIDER: S-EPMC4647393 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of [(2S,3R)-3-hy-droxy-3-phenyl-butan-2-yl]pyrrolidinium chloride.

Kandhaswamy Abirami A Meena K S KS Deepa S S Murugavel S S

Acta crystallographica. Section E, Crystallographic communications 20150917 Pt 10

In the title mol-ecular salt, C14H22NO(+)·Cl(-), the pyrrolidinium ring adopts a twisted conformation about one of the N-C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N-C-C-Car (ar = aromatic) linkage is 163.74 (15)°. In the crystal, the components are linked via N-H⋯Cl and O-H⋯Cl hydrogen bonds, forming zigzig chains along the b-axis direction. These chains are connected along the c axis by very weak C-H⋯π inter-acti ...[more]

PMID: 26594461

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