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Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl-idene]aniline.

ABSTRACT: The title compound, C12H9N3O2, adopts an E conformation at the imine double bond. The pyridyl ring makes a dihedral angle of 47.78?(5)° with the benzene ring, indicating the mol-ecule is twisted. In the crystal, mol-ecules are ?-? stacked into columns parallel to [100], with an inter-planar separation of 3.8537?(8)?Å, corresponding to the length of the a axis. The chains are further linked via weak C-H?O and C-H?N hydrogen bonds, forming two-dimensional sheets parallel to (010). The sheets interact by van der Waals inter-actions.

SUBMITTER: Saphu W

PROVIDER: S-EPMC4647417 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl-idene]aniline.

Saphu Watcharin W Chainok Kittipong K

Acta crystallographica. Section E, Crystallographic communications 20150917 Pt 10

The title compound, C12H9N3O2, adopts an E conformation at the imine double bond. The pyridyl ring makes a dihedral angle of 47.78 (5)° with the benzene ring, indicating the mol-ecule is twisted. In the crystal, mol-ecules are π-π stacked into columns parallel to [100], with an inter-planar separation of 3.8537 (8) Å, corresponding to the length of the a axis. The chains are further linked via weak C-H⋯O and C-H⋯N hydrogen bonds, forming two-dimensional sheets parallel to (010). The sheets inter ...[more]

PMID: 26594463

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