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Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclo-pentyl-idenehydrazin-1-yl-idene)-4-oxo-3-phenyl-1,3-thia-zolidin-5-yl-idene]ethano-ate.

ABSTRACT: In the title compound, C17H17N3O3S, the cyclo-pentane ring is disordered over two sets of sites with an occupancy ratio of 0.775?(8):0.225?(8) for the affected atoms. The thia-zolidinyl ring is planar (r.m.s. deviation = 0.024?Å) and forms a dihedral angle of 65.13?(8)° with the attached phenyl ring. The mol-ecular packing is stabilized by C-H?O and C-H?? inter-actions, forming a three-dimensional structure.

SUBMITTER: Akkurt M

PROVIDER: S-EPMC4647441 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclo-pentyl-idenehydrazin-1-yl-idene)-4-oxo-3-phenyl-1,3-thia-zolidin-5-yl-idene]ethano-ate.

Akkurt Mehmet M Smolenski Victoria A VA Mohamed Shaaban K SK Jasinski Jerry P JP Hassan Alaa A AA Albayati Mustafa R MR

Acta crystallographica. Section E, Crystallographic communications 20150926 Pt 10

In the title compound, C17H17N3O3S, the cyclo-pentane ring is disordered over two sets of sites with an occupancy ratio of 0.775 (8):0.225 (8) for the affected atoms. The thia-zolidinyl ring is planar (r.m.s. deviation = 0.024 Å) and forms a dihedral angle of 65.13 (8)° with the attached phenyl ring. The mol-ecular packing is stabilized by C-H⋯O and C-H⋯π inter-actions, forming a three-dimensional structure. ...[more]

PMID: 26594474

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Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl-phen-yl)ethyl-idene]hydrazinyl-idene}-4-oxo-3-phenyl-1,3-thia-zolidin-5-yl-idene)ethano-ate.

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Dimethyl (2Z)-2-[4-((1Z)-1-{2-[(2Z,5Z)-5-(2-meth-oxy-2-oxo-ethyl-idene)-4-oxo-3-phenyl-1,3-thia-zolidin-2-yl-idene]hydra-zin-1-yl-idene}eth-yl)anilino]but-2-ene-dio-ate.

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