Easy access to heterobimetallic complexes for medical imaging applications via microwave-enhanced cycloaddition.
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ABSTRACT:
SUBMITTER: Desbois N
PROVIDER: S-EPMC4660971 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:Design of interface-controllable magnetic composite towards the wideband microwave absorber is greatly significance, however, it still remains challenging. Herein, we designed a spherical-like hybrids, using the Co3O4 and amorphous carbon as the core and shell, respectively. Then, the existed Co3O4 core could be totally reduced by the carbon shell, thus in CoxOy core (composed by Co and Co3O4). Of particular note, the ratios of Co and Co3O4 can be linearly tuned, suggesting the controlled interfaces, which greatly influences the interface loss behavior and electromagnetic absorption performance. The results revealed that the minimum reflection loss value (RLmin) of -39.4 dB could be achieved for the optimal CoxOy@C sample under a thin thickness of 1.4 mm. More importantly, the frequency region with RL < -10 dB was estimated to be 4.3 GHz, ranging from 13.7 to 18.0 GHz. The superior wideband microwave absorption performance was primarily attributed to the multiple interfacial polarization and matched impedance matching ability.
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Project description:The ever-increasing interest towards metamaterial absorbers owes to its remarkable features such as ultra-thin nature and design flexibility. Subduing the inherent narrow bandwidth of such absorbers is the prime goal in metamaterial absorber research, as this can widen the applications areas. A greater challenge is to construct bidirectional absorber, which provides direction-insensitive absorption, as most of the existing designs exhibit single sided absorption due to the complete metal film used in the design. This work presents the realization of a bidirectional, bandwidth-enhanced metamaterial absorber with basic elements such as strips and squares optimized to have adjacent resonances leading to a bandwidth-enhanced absorption. The structural evolution of the constituent metallic components towards the formation of bandwidth-enhanced absorption is described. The bidirectional absorber exhibits more than 90% absorption between 13.40 GHz and 14.25 GHz from the two incident directions. The mechanism of absorption is studied with the surface current analysis and the effective parameters of the structure. The choice of the metallic components with four-fold rotation symmetry renders the proposed design to be polarization independent and wide-angle receptive. The numerical studies are verified experimentally at microwave frequencies, which shows a good agreement between them.
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Project description:BackgroundClinical information systems frequently use intranet and Internet technologies. However these technologies have emphasized sharing and not security, despite the sensitive and private nature of much health information. Digital certificates (electronic documents which recognize an entity or its attributes) can be used to control access in clinical intranet applications.ObjectivesTo outline the need for access control in distributed clinical database systems, to describe the use of digital certificates and security policies, and to propose the architecture for a system using digital certificates, cryptography and security policy to control access to clinical intranet applications.MethodsWe have previously developed a security policy, DIMEDAC (Distributed Medical Database Access Control), which is compatible with emerging public key and privilege management infrastructure. In our implementation approach we propose the use of digital certificates, to be used in conjunction with DIMEDAC.ResultsOur proposed access control system consists of two phases: the ways users gain their security credentials; and how these credentials are used to access medical data. Three types of digital certificates are used: identity certificates for authentication; attribute certificates for authorization; and access-rule certificates for propagation of access control policy. Once a user is identified and authenticated, subsequent access decisions are based on a combination of identity and attribute certificates, with access-rule certificates providing the policy framework.ConclusionsAccess control in clinical intranet applications can be successfully and securely managed through the use of digital certificates and the DIMEDAC security policy.
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