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Homogeneity of lithium distribution in cylinder-type Li-ion batteries.

ABSTRACT: Spatially-resolved neutron powder diffraction with a gauge volume of 2?×?2?×?20?mm(3) has been applied as an in situ method to probe the lithium concentration in the graphite anode of different Li-ion cells of 18650-type in charged state. Structural studies performed in combination with electrochemical measurements and X-ray computed tomography under real cell operating conditions unambiguously revealed non-homogeneity of the lithium distribution in the graphite anode. Deviations from a homogeneous behaviour have been found in both radial and axial directions of 18650-type cells and were discussed in the frame of cell geometry and electrical connection of electrodes, which might play a crucial role in the homogeneity of the lithium distribution in the active materials within each electrode.

SUBMITTER: Senyshyn A

PROVIDER: S-EPMC4683395 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature

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Homogeneity of lithium distribution in cylinder-type Li-ion batteries.

Senyshyn A A Mühlbauer M J MJ Dolotko O O Hofmann M M Ehrenberg H H

Scientific reports 20151218

Spatially-resolved neutron powder diffraction with a gauge volume of 2 × 2 × 20 mm(3) has been applied as an in situ method to probe the lithium concentration in the graphite anode of different Li-ion cells of 18650-type in charged state. Structural studies performed in combination with electrochemical measurements and X-ray computed tomography under real cell operating conditions unambiguously revealed non-homogeneity of the lithium distribution in the graphite anode. Deviations from a homogene ...[more]

PMID: 26681110

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