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Crystal structure of (RS)-(4-chloro-phen-yl)(pyridin-2-yl)methanol.

ABSTRACT: In the title racemic compound, C12H10ClNO, the dihedral angle between the benzene and pyridine rings is 74.34?(6)°. In the crystal, the mol-ecules are linked by O-H?N hydrogen bonds, forming zigzag C(5) [001] chains in which alternating R- and S-configuration mol-ecules are related by c-glide symmetry. In addition, inversion-related pairs of mol-ecules are linked into dimers by pairs of weak C-Cl??(pyrid-yl) inter-actions, which link the hydrogen-bonded chains into (100) sheets. Structural comparisons are drawn with a number of related compounds.

SUBMITTER: Narayana B

PROVIDER: S-EPMC4704747 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of (RS)-(4-chloro-phen-yl)(pyridin-2-yl)methanol.

Narayana Badiadka B Sarojini Balladka K BK Yathirajan Hemmige S HS Rathore Ravindranath R Glidewell Christopher C

Acta crystallographica. Section E, Crystallographic communications 20160101 Pt 1

In the title racemic compound, C12H10ClNO, the dihedral angle between the benzene and pyridine rings is 74.34 (6)°. In the crystal, the mol-ecules are linked by O-H⋯N hydrogen bonds, forming zigzag C(5) [001] chains in which alternating R- and S-configuration mol-ecules are related by c-glide symmetry. In addition, inversion-related pairs of mol-ecules are linked into dimers by pairs of weak C-Cl⋯π(pyrid-yl) inter-actions, which link the hydrogen-bonded chains into (100) sheets. Structural compa ...[more]

PMID: 26870589

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