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Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)cobalt(II).

ABSTRACT: The structure of the mononuclear title complex, [{(H3CS)2C=NC N}2CoCl2], consists of a Co(II) atom coordinated in a distorted tetra-hedral manner by two Cl(-) ligands and the terminal N atoms of two dimethyl N-cyano-dithio-imino-carbonate ligands. The two organic ligands are almost coplanar, with a dihedral angle of 5.99?(6)° between their least-squares planes. The crystal packing features pairs of inversion-related complexes that are held together through C-H?Cl and C-H?S inter-actions and ?-? stacking [centroid-to-centroid distance = 3.515 (su?) Å]. Additional C-H?Cl and C-H?S inter-actions, as well as Cl?S contacts < 3.6?Å, consolidate the crystal packing.

SUBMITTER: Diop MB

PROVIDER: S-EPMC4704751 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)cobalt(II).

Diop Mouhamadou Birame MB Diop Libasse L Oliver Allen G AG

Acta crystallographica. Section E, Crystallographic communications 20160101 Pt 1

The structure of the mononuclear title complex, [{(H3CS)2C=NC N}2CoCl2], consists of a Co(II) atom coordinated in a distorted tetra-hedral manner by two Cl(-) ligands and the terminal N atoms of two dimethyl N-cyano-dithio-imino-carbonate ligands. The two organic ligands are almost coplanar, with a dihedral angle of 5.99 (6)° between their least-squares planes. The crystal packing features pairs of inversion-related complexes that are held together through C-H⋯Cl and C-H⋯S inter-actions and π-π ...[more]

PMID: 26870588

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