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Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(?(5)-C5H4 (c) C4H3 NPh)(?(5)-C5H5)].

ABSTRACT: The mol-ecular structure of the title compound, [Fe(C5H5)(C15H12N)], consists of a ferrocene moiety with an N-phenyl-pyrrole heterocycle bound to one cyclo-penta-dienyl ring. The 1,3-disubstitution of the pyrrole results in an L-shaped arrangement of the mol-ecule with plane inter-sections of 2.78?(17)° between the pyrrole and the N-bonded phenyl ring and of 8.17?(18)° between the pyrrole and the cyclo-penta-dienyl ring. In the crystal, no remarkable inter-molecular inter-actions are observed.

SUBMITTER: Pfaff U

PROVIDER: S-EPMC4704767 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C5H4 (c) C4H3 NPh)(η(5)-C5H5)].

Pfaff Ulrike U Korb Marcus M Lang Heinrich H

Acta crystallographica. Section E, Crystallographic communications 20160101 Pt 1

The mol-ecular structure of the title compound, [Fe(C5H5)(C15H12N)], consists of a ferrocene moiety with an N-phenyl-pyrrole heterocycle bound to one cyclo-penta-dienyl ring. The 1,3-disubstitution of the pyrrole results in an L-shaped arrangement of the mol-ecule with plane inter-sections of 2.78 (17)° between the pyrrole and the N-bonded phenyl ring and of 8.17 (18)° between the pyrrole and the cyclo-penta-dienyl ring. In the crystal, no remarkable inter-molecular inter-actions are observed. ...[more]

PMID: 26870594

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