Ontology highlight
ABSTRACT:
SUBMITTER: Marx VM
PROVIDER: S-EPMC4713124 | biostudies-literature | 2015 Feb
REPOSITORIES: biostudies-literature
Marx Vanessa M VM Sullivan Alexandra H AH Melaimi Mohand M Virgil Scott C SC Keitz Benjamin K BK Weinberger David S DS Bertrand Guy G Grubbs Robert H RH
Angewandte Chemie (International ed. in English) 20141217 6
An expanded family of ruthenium-based metathesis catalysts bearing cyclic alkyl amino carbene (CAAC) ligands was prepared. These catalysts exhibited exceptional activity in the ethenolysis of the seed-oil derivative methyl oleate. In many cases, catalyst turnover numbers (TONs) of more than 100,000 were achieved, at a catalyst loading of only 3 ppm. Remarkably, the most active catalyst system was able to achieve a TON of 340,000, at a catalyst loading of only 1 ppm. This is the first time a seri ...[more]