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Crystal structure of piperazine-1,4-diium bis-(4-amino-benzene-sulfonate).

ABSTRACT: The asymmetric unit of the title salt, C4H12N2 (2+)·2C6H6NO3S(-), consists of half a piperazindiium dication, located about an inversion centre, and a 4-amino-benzene-sulfonate anion. The piperazine ring adopts a chair conformation. In the crystal, the cations and anions are linked via N-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional framework. Within the framework there are C-H⋯π inter-actions and the N-H⋯O hydrogen bonds result in the formation of R 4 (4)(22) and R 3 (4)(13) ring motifs.

SUBMITTER: Kumar KS

PROVIDER: S-EPMC4719991 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Crystal structure of 2-methyl-piperazine-1,4-diium bis-(hydrogen maleate).

Project description:In the title salt, C5H14N2 (2+)·2C4H3O4 (-), the asymmetric unit contains two independent 2-methyl-piperazinium dications, which comprise a racemic pair, and four hydrogen maleate monoanions. In the roughly planar hydrogen maleate anions, intra-molecular O-H⋯O hydrogen bonds generate S(7) rings. In the crystal, the four independent anions are linked to the 2-methyl-piperazinium cations through N-H⋯O hydrogen bonds, forming two-dimensional layered structures lying parallel to (001).

| S-EPMC4350694 | biostudies-literature

Crystal structure of 1,4-bis-(3-ammonio-prop-yl)piperazine-1,4-diium bis-[dichromate(VI)].

Project description:The asymmetric unit of the organic-inorganic title salt, (C10H28N4)[Cr2O7]2, comprises one half of an 1,4-bis-(3-ammonio-prop-yl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO4 tetra-hedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N-H⋯O hydrogen bonds between the cations and anions and additional C-H⋯O inter-actions lead to the formation of a three-dimensional network structure.

| S-EPMC4908532 | biostudies-literature

Piperazine-1,4-diium bis-(perchlorate) dihydrate.

Project description:The asymmetric unit of the title compound, C(4)H(12)N(2) (2+)·2ClO(4) (-)·2H(2)O, contains half of a piperazinediium cation, one perchlorate anion and one water mol-ecule. The diprotonated piperazine ring, which is completed by crystallographic inversion symmetry, adopts a chair conformation. In the crystal structure, the cations and anions are linked by inter-molecular N-H⋯O and O-H⋯O hydrogen bonds into a three-dimensional network.

| S-EPMC3007905 | biostudies-literature

Piperazine-1,4-diium bis-(3,5-dicarboxy-benzoate).

Project description:The asymmetric unit of the title salt, C(4)H(12)N(2) (2+)·2C(9)H(5)O(6) (-), comprises one half of the piperazine-1,4-diium dication lying on an inversion centre and one 3,5-dicarboxy-benzoate anion. In the crystal, the ions are linked into a two-dimensional framework parallel to (101) by N-H?O and O-H?O hydrogen bonds.

| S-EPMC2979046 | biostudies-literature

trans-2,5-Di-methyl-piperazine-1,4-diium bis(perchlorate) dihydrate: crystal structure and Hirshfeld surface analysis.

Project description:The asymmetric unit of the title hydrated mol-ecular salt, C6H16N2 (2+)·2ClO4 (-)·2H2O, contains a half dication (completed by inversion symmetry), a perchlorate anion and a water mol-ecule. The extended structure consists of infinite chains of formula [(ClO4)H2O] n (n) (-) ions extending along the b axis linked by Ow-H?O (w = water) hydrogen bonds. These chains are cross-linked by the dications via N-H?Ow and weak C-H?O hydrogen bonds, thus forming a three-dimensional supra-molecular network. Three-dimensional Hirshfeld surface analysis and two-dimensional fingerprint maps reveal that the structure is dominated by H?O/O?H and H?H contacts.

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6-Amino-9H-purine-1,7-diium bis-(4-methyl-benzene-sulfonate) monohydrate.

Project description:The asymmetric unit of the title compound, C(5)H(7)N(5) (2+)·2C(7)H(7)O(3)S(-)·H(2)O, consists of one diprotonated adeninium cation, two p-toluene-sulfonic acid anions and one water mol-ecule. In the crystal, the cations and anions are connected through N-H?O hydrogen bonds forming R(2) (2)(8) and R(2) (2)(9) graph-set motifs. The solvent water mol-ecule links cations and anions through O-H?O and N-H?O hydrogen bonds, generating a two-dimensional layer parallel to (10).

| S-EPMC2979717 | biostudies-literature

1,4-Diferrocenyl-2-methyl-piperazine-1,4-diium bis-(trifluoro-acetate).

Project description:In the title compound, [Fe(2)(C(5)H(5))(2)(C(17)H(24)N(2))](CF(3)COO)(2), the cation possesses a crystallographically imposed inversion centre. The methyl group is disordered over two positions of equal occupancy. The Fe-C bond lengths to the two cyclo-penta-diene rings vary from 2.025?(6) to 2.044?(6)?Å. Inter-molecular N-H?O and C-H?O hydrogen bonds link the cations and anions into a three-dimensional network.

| S-EPMC2977395 | biostudies-literature

1,4-Dimethyl-piperazine-1,4-diium bis-(hexa-fluoro-phosphate) dihydrate.

Project description:In the title hydrated mol-ecular salt, C(6)H(16)N(2) (+)·2PF(6) (-)·2H(2)O, the complete 1,4-dimethyl-piperazine-1,4-diium dication is generated by crystallographic inversion symmetry and both C-N bonds are in equatorial orientations. In the crystal, the components are linked by O-H?F and N-H?O hydrogen bonds but there are no direct links between cations and anions.

| S-EPMC3344619 | biostudies-literature

1-Phenyl-piperazine-1,4-diium bis-(hydrogen sulfate).

Project description:In the title compound, C(10)H(16)N(2) (2+)·2HSO(4) (-), the S atoms adopt slightly distorted tetra-hedral geometry and the diprotonated piperazine ring adopts a chair conformation. In the crystal, the 1-phenyl-piperazine-1,4-diium cations are anchored between chains formed by the sulfate entities via inter-molecular bifurcated N-H?(O,O) and weak C-H?O hydrogen bonds. These hydrogen bonds contribute to the cohesion and stability of the network of the crystal structure.

| S-EPMC2983403 | biostudies-literature

1-Benzyl-piperazine-1,4-diium bis-(perchlorate) monohydrate.

Project description:In the title compound, C(11)H(18)N(2) (2+)·2ClO(4) (-)·H(2)O, one perchlor-ate anion is disordered over two orientations in a 0.66?(3):0.34?(3) ratio. Inter-molecular O-H?O, N-H?O and C-H?O hydrogen bonds link the cations, anions and water mol-ecules into ribbons extending along [100].

| S-EPMC3006781 | biostudies-literature

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