Ontology highlight
ABSTRACT:
SUBMITTER: Hryniewicka A
PROVIDER: S-EPMC4734414 | biostudies-literature | 2015
REPOSITORIES: biostudies-literature
Hryniewicka Agnieszka A Suchodolski Szymon S Wojtkielewicz Agnieszka A Morzycki Jacek W JW Witkowski Stanisław S
Beilstein journal of organic chemistry 20151230
The synthesis of a new type of Hoveyda-Grubbs 2(nd) generation catalyst bearing a modified N-heterocyclic carbene ligands is reported. The new catalyst contains an NHC ligand symmetrically substituted with chromanyl moieties. The complex was tested in model CM and RCM reactions. It showed very high activity in CM reactions with electron-deficient α,β-unsaturated compounds even at 0 °C. It was also examined in more demanding systems such as conjugated dienes and polyenes. The catalyst is stable, ...[more]