Ontology highlight
ABSTRACT:
SUBMITTER: Wappel J
PROVIDER: S-EPMC4734425 | biostudies-literature | 2016
REPOSITORIES: biostudies-literature
Wappel Julia J Fischer Roland C RC Cavallo Luigi L Slugovc Christian C Poater Albert A
Beilstein journal of organic chemistry 20160128
A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered N,O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands. The innovative pre-catalysts were tested regarding their behavior in ROMP and especially for their use in the synthesis of poly(dicyclopentadiene) (pDCPD). Bearing either the common phosphine leaving ligand in the first and second Grubbs olefin metathesis catalysts, or the Ru-O bond ...[more]