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Polymer/Nanoparticle Hybrid Materials of Precise Dimensions by Size-Exclusive Fishing of Metal Nanoparticles.


ABSTRACT: Polymer cages prepared by etching of gold nanoparticles from polymer templates by the "grafting around" method are designed for selective separation of metal nanoparticles. The separation process is demonstrated as a fast biphasic ligand exchange reaction. The high separation efficiency and size selectivity of the polymer cage is verified by comparison with the linear block copolymer.

SUBMITTER: Fan Z 

PROVIDER: S-EPMC4745003 | biostudies-literature | 2015 Jul

REPOSITORIES: biostudies-literature

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Polymer/Nanoparticle Hybrid Materials of Precise Dimensions by Size-Exclusive Fishing of Metal Nanoparticles.

Fan Ziyin Z   Serrano Melissa Köhn MK   Schaper Andreas A   Agarwal Seema S   Greiner Andreas A  

Advanced materials (Deerfield Beach, Fla.) 20150521 26


Polymer cages prepared by etching of gold nanoparticles from polymer templates by the "grafting around" method are designed for selective separation of metal nanoparticles. The separation process is demonstrated as a fast biphasic ligand exchange reaction. The high separation efficiency and size selectivity of the polymer cage is verified by comparison with the linear block copolymer. ...[more]

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