Ontology highlight
ABSTRACT:
SUBMITTER: Taylor RG
PROVIDER: S-EPMC4755154 | biostudies-literature | 2016 Feb
REPOSITORIES: biostudies-literature
Taylor Rupert G D RG Bezzu C Grazia CG Carta Mariolino M Msayib Kadhum J KJ Walker Jonathan J Short Rhys R Kariuki Benson M BM McKeown Neil B NB
Chemistry (Weinheim an der Bergstrasse, Germany) 20160111 7
Efficient reactions between fluorine-functionalised biphenyl and terphenyl derivatives with catechol-functionalised terminal groups provide a route to large, discrete organic molecules of intrinsic microporosity (OMIMs) that provide porous solids solely by their inefficient packing. By altering the size and substituent bulk of the terminal groups, a number of soluble compounds with apparent BET surface areas in excess of 600 m(2) g(-1) are produced. The efficiency of OMIM structural units for g ...[more]