Dataset Information

Efficient design, accurate fabrication and effective characterization of plasmonic quasicrystalline arrays of nano-spherical particles.

ABSTRACT: In this paper, the scattering properties of two-dimensional quasicrystalline plasmonic lattices are investigated. We combine a newly developed synthesis technique, which allows for accurate fabrication of spherical nanoparticles, with a recently published variation of generalized multiparticle Mie theory to develop the first quantitative model for plasmonic nano-spherical arrays based on quasicrystalline morphologies. In particular, we study the scattering properties of Penrose and Ammann- Beenker gold spherical nanoparticle array lattices. We demonstrate that by using quasicrystalline lattices, one can obtain multi-band or broadband plasmonic resonances which are not possible in periodic structures. Unlike previously published works, our technique provides quantitative results which show excellent agreement with experimental measurements.

SUBMITTER: Namin FA

PROVIDER: S-EPMC4766558 | biostudies-literature | 2016 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Efficient design, accurate fabrication and effective characterization of plasmonic quasicrystalline arrays of nano-spherical particles.

Namin Farhad A FA Yuwen Yu A YA Liu Liu L Panaretos Anastasios H AH Werner Douglas H DH Mayer Theresa S TS

Scientific reports 20160225

In this paper, the scattering properties of two-dimensional quasicrystalline plasmonic lattices are investigated. We combine a newly developed synthesis technique, which allows for accurate fabrication of spherical nanoparticles, with a recently published variation of generalized multiparticle Mie theory to develop the first quantitative model for plasmonic nano-spherical arrays based on quasicrystalline morphologies. In particular, we study the scattering properties of Penrose and Ammann- Beenk ...[more]

PMID: 26911709

Similar Datasets

Project description:Octahedral anatase particles (OAPs), prepared by ultrasonication-hydrothermal reaction (US-HT), were modified with 2 wt% of gold by photodeposition. Conditions of US-HT process such as durations of US and durations of HT were varied to obtain OAPs products different by physicochemical and morphological properties. Au/OAPs samples were characterized by X-ray diffraction (XRD), scanning transmission electron microscopy (STEM), X-ray photoelectron spectroscopy (XPS) and diffuse reflectance spectroscopy (DRS). The photocatalytic activity was tested under UV irradiation for decomposition of acetic acid (CO2 system) and dehydrogenation of methanol (H2 system) under aerobic and anaerobic conditions, respectively, and for oxidation of 2-propanol under visible light irradiation. Photodeposition of gold was very fast for all OAPs samples (0.5-10 min) under Ar atmosphere, and the clear correlation between the content of electron traps (ETs) and the induction period, during which nanoparticles (NPs) of gold are formed, indicates that ETs in titania samples are a key-factor for rapidity of gold photodeposition on titania surface. It was found that better morphology of titania (larger content of faceted particles) resulted in formation of larger gold NPs, while small gold NPs were deposited on structural defects. Modification of OAPs with gold NPs resulted in significant enhancement of photocatalytic activity, being e.g., 1.5 (CO2 system), 7.7 (H2 system), and even more than 40 under vis irradiation. It was found that both the properties of titania and gold are crucial for resultant photocatalytic activity, but a direct correlation between one structural/physical property and photocatalytic activity could not be obtained since all structural properties changed simultaneously when conditions of photocatalyst preparation (US-HT) were changed. Therefore, gold NPs of controlled sizes were deposited on OAPs product with the best morphology by modified photodeposition method. Clear correlation between photocatalytic activity under visible light and the size of gold NPs indicates that gold properties are decisive for visible light activity rather than titania properties. 3D-FDTD simulations confirm that an increase in the size of gold NPs results in extended surface areas with field enhancement.

Project description:Plasmonic nanostructures are important across diverse applications from sensing to renewable energy. Periodic porous array structures are particularly attractive because such topography offers a means to encapsulate or capture solution phase species and combines both propagating and localised plasmonic modes offering versatile addressability. However, in analytical spectroscopic applications, periodic pore arrays have typically reported weaker plasmonic signal enhancement compared to particulate structures. This may be addressed by introducing additional nano-structuring into the array to promote plasmonic coupling that promotes electric field-enhancement, whilst retaining pore structure. Introducing nanoparticle structures into the pores is a useful means to promote such coupling. However, current approaches rely on either expensive top-down methods or on bottom-up methods that yield random particle placement and distribution. This report describes a low cost, top-down technique for preparation of nano-sub-structured plasmonic pore arrays in a highly reproducible manner that can be applied to build arrays extending over macroscopic areas of mm2 to cm2. The method exploits oxygen plasma etching, under controlled conditions, of the cavity encapsulated templating polystyrene (PS) spheres used to create the periodic array. Subsequent metal deposition leads to reproducible nano-structuring within the wells of the pore array, coined in-cavity nanoparticles (icNPs). This approach was demonstrated across periodic arrays with pore/sphere diameters ranging from 500 nm to 3 μm and reliably improved the plasmonic properties of the substrate across all array dimensions compared to analogous periodic arrays without the nano-structuring. The enhancement factors achieved for metal enhanced emission and surface enhanced Raman spectroscopy depended on the substrate dimensions, with the best performance achieved for nanostructured 2 μm diameter pore arrays, where a more than 104 improvement over Surface Enhanced Raman Spectroscopy (SERS) and 200-fold improvement over Metal Enhanced Fluorescence (MEF) were observed for these substrates compared with analogous unmodified pore arrays. The experiments were supported by Finite-Difference Time-Domain (FDTD) calculations used to simulate the electric field distribution as a function of pore nano-structuring.

Dataset Information

Efficient design, accurate fabrication and effective characterization of plasmonic quasicrystalline arrays of nano-spherical particles.

Publications

Efficient design, accurate fabrication and effective characterization of plasmonic quasicrystalline arrays of nano-spherical particles.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets