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Synthesis and Utility of Dihydropyridine Boronic Esters.


ABSTRACT: When activated by an acylating agent, pyridine boronic esters react with organometallic reagents to form a dihydropyridine boronic ester. This intermediate allows access to a number of valuable substituted pyridine, dihydropyridine, and piperidine products.

SUBMITTER: Panda S 

PROVIDER: S-EPMC4769604 | biostudies-literature | 2016 Feb

REPOSITORIES: biostudies-literature

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Synthesis and Utility of Dihydropyridine Boronic Esters.

Panda Santanu S   Coffin Aaron A   Nguyen Q Nhu QN   Tantillo Dean J DJ   Ready Joseph M JM  

Angewandte Chemie (International ed. in English) 20151222 6


When activated by an acylating agent, pyridine boronic esters react with organometallic reagents to form a dihydropyridine boronic ester. This intermediate allows access to a number of valuable substituted pyridine, dihydropyridine, and piperidine products. ...[more]

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