Ontology highlight
ABSTRACT:
SUBMITTER: Nafe J
PROVIDER: S-EPMC4797621 | biostudies-literature | 2015 Nov
REPOSITORIES: biostudies-literature
Nafe Julia J Auras Florian F Karaghiosoff Konstantin K Bein Thomas T Knochel Paul P
Organic letters 20151015 21
The tetrathiafulvalene-scaffold (TTF) reacts selectively in allylation, acylation, arylation, halogenation, and thiolation reactions via magnesium or zinc derivatives that are obtained by a direct metalation with Mg- and Zn-TMP-bases (TMP = 2,2,6,6-tetramethylpiperidyl). This stepwise functionalization provides access to a range of new mono-, di-, tri-, and tetra-functionalized TTF-derivatives and allows for fine-tuning of their energy levels. ...[more]