Ontology highlight
ABSTRACT:
SUBMITTER: Pili S
PROVIDER: S-EPMC4882730 | biostudies-literature | 2016 May
REPOSITORIES: biostudies-literature
Pili Simona S Argent Stephen P SP Morris Christopher G CG Rought Peter P García-Sakai Victoria V Silverwood Ian P IP Easun Timothy L TL Li Ming M Warren Mark R MR Murray Claire A CA Tang Chiu C CC Yang Sihai S Schröder Martin M
Journal of the American Chemical Society 20160516 20
Understanding the molecular mechanism of proton conduction is crucial for the design of new materials with improved conductivity. Quasi-elastic neutron scattering (QENS) has been used to probe the mechanism of proton diffusion within a new phosphonate-based metal-organic framework (MOF) material, MFM-500(Ni). QENS suggests that the proton conductivity (4.5 × 10(-4) S/cm at 98% relative humidity and 25 °C) of MFM-500(Ni) is mediated by intrinsic "free diffusion inside a sphere", representing the ...[more]